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January 09, 2014 AT 3:48 AM
It's a good thing Nina Dobrev and Ian Somerhalder came prepared. The former couple joked about their "Best Chemistry" win at the People's Choice Awards in L.A. on Wednesday, by humorously addressing the elephant in the room. Somerhalder, 35, said while accepting the TV award, "At the beginning of the Vampire Diaries, Nina's character Elena actually hated my character Damon." And then we started dating on the show," Dobrev, 25, added.